Next-Generation Electronic Devices: Conduction, Surface States in Topological Insulator Nanoribbons Controlled

Perhaps most importantly, the surfaces of topological insulators enable the transport of spin-polarized electrons while preventing the"scattering" typically associated with power consumption, in which electrons deviate from their trajectory, resulting in dissipation.

Because of such characteristics, these materials hold great potential for use in future transistors, memory devices and magnetic sensors that are highly energy efficient and require less power.

In a study published Feb. 13 inNature Nanotechnology, researchers from UCLA's Henry Samueli School of Engineering and Applied Science and from the materials division of Australia's University of Queensland show the promise of surface-conduction channels in topological insulator nanoribbons made of bismuth telluride and demonstrate that surface states in these nanoribbons are"tunable" -- able to be turned on and off depending on the position of the Fermi level.

"Our finding enables a variety of opportunities in building potential new-generation, low-dissipation nanoelectronic and spintronic devices, from magnetic sensing to storage," said Kang L. Wang, the Raytheon Professor of Electrical Engineering at UCLA Engineering, whose team carried out the research.

Bismuth telluride is well known as a thermoelectric material and has also been predicted to be a three-dimensional topological insulator with robust and unique surface states. Recent experiments with bismuth telluride bulk materials have also suggested two-dimensional conduction channels originating from the surface states. But it has been a great challenge to modify surface conduction, because of dominant bulk contribution due to impurities and thermal excitations in such small-band-gap semiconductors.

The development of topological insulator nanoribbons has helped. With their large surface-to-volume ratios, these nanoribbons significantly enhance surface conditions and enable surface manipulation by external means.

Wang and his team used thin bismuth telluride nanoribbons as conducting channels in field-effect transistor structures. These rely on an electric field to control the Fermi level and hence the conductivity of a channel. The researchers were able to demonstrate for the first time the possibility of controlling surface states in topological insulator nanostructures.

"We have demonstrated a clear surface conduction by partially removing the bulk conduction using an external electric field," said Faxian Xiu, a UCLA staff research associate and lead author of the study."By properly tuning the gate voltage, very high surface conduction was achieved, up to 51 percent, which represents the highest values in topological insulators."

"This research is very exciting because of the possibility to build nanodevices with a novel operating principle," said Wang, who is also associate director of the California NanoSystems Institute (CNSI) at UCLA."Very similar to the development of graphene, the topological insulators could be made into high-speed transistors and ultra-high-sensitivity sensors."

The new findings shed light on the controllability of the surface spin states in topological insulator nanoribbons and demonstrate significant progress toward high surface electric conditions for practical device applications. The next step for Wang's team is to produce high-speed devices based on their discovery.

"The ideal scenario is to achieve 100 percent surface conduction with a complete insulating state in the bulk," Xiu said."Based on the current work, we are targeting high-performance transistors with power consumption that is much less than the conventional complementary metal-oxide semiconductors (CMOS) technology used typically in today's electronics."

Study collaborators Jin Zou, a professor of materials engineering at the University of Queensland; Yong Wang, a Queensland International Fellow; and Zou's team at the division of materials at the University of Queensland contributed significantly to this work. A portion of the research was also done in Alexandros Shailos' lab at UCLA.

The study was funded by the Focus Center Research Program -- Center on Functional Engineered Nano Architectonics (FENA) at UCLA Engineering; the U.S. Defense Advanced Research Projects Agency (DARPA); and the Australian Research Council. The research on topological insulators was pioneered by FENA's Shoucheng Zhang, a professor of physics at Stanford University.

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Getting Cars Onto the Road Faster

The auto industry faces major challenges. New models are entering the market at ever shorter intervals, products are becoming more complex, and the trend towards electric cars requires modified vehicle structures. European production sites are coming under increasing cost pressure from low-wage countries. Cost reductions, shorter production times, new materials and innovative assembly techniques are needed if companies are to remain competitive. To achieve these goals, 23 business and research organizations are participating in the EU's Pegasus project (www.pegasus-eu.net). One of the research partners is the Fraunhofer Institute for Chemical Technology ICT in Pfinztal, which is contributing its expertise in the polymer engineering sector. The project partners have jointly developed a software platform to reduce development times and costs.

The Integrated Design and Engineering Environment (IDEE) is a CAD/CAE/CAM software system which is connected to an intelligent database. It analyzes the functional requirements of a product and identifies appropriate materials at an early stage of the development process. If, for example, a car roof is to be made in a different material than before, it is not necessary to conduct a new development process. Instead, the design engineers enter the component data into the software system, which assesses the information and then selects suitable materials and manufacturing processes. The platform also provides engineering guidelines for designing the tools that will be used to produce the component. The project partners have demonstrated how this platform could work on the example of a fender with integrated LED tail light."We used the original fender from a Smart. Our project demonstrates how this complex component can be produced more quickly and cheaply with new processing techniques, materials, bonding agents and tools," says Timo Huber, a scientist at Fraunhofer ICT. Instead of conventional lamps, the project partners fitted LED tail lights to the fender. This reduced the number of separate parts from eight to five, and the number of processing steps from twelve to five. Material and cost savings were also achieved by using conductor paths made of electrically conductive polymer. The conductive carbon nanotubes conduct the electricity from the connector to the LEDs and render metallic conductor structures superfluous.

A further example application: So that components such as the LED tail lights can be dismantled more quickly, they are bonded using a special adhesive. For this the research scientists at Fraunhofer ICT and their project partners developed a new microwave-active adhesive bonding system. When irradiated with microwaves the individual components lose their adhesion and can be easily taken apart. This means that parts can be efficiently recycled into different categories."In addition, we dyed the fender using newly developed pigments based on special nanoparticles," states Huber. These nanostructures can be worked in particularly evenly, to dye plastics such as polypropylene. This means fewer pigments are needed than usual."We have also taken the importance of protecting the climate into account. Further developments in local fiber reinforcement of structural vehicle components will reduce weight and therefore emissions of CO2," the scientist adds, and sums up:"All in all the IDEE system will shorten development times, cut the number of assembly steps and reduce the amount of material consumed." IDEE is still under development, but it can already be used to produce simple components. The software should be ready and available to the auto industry in about a year's time.

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Engineers Grow Nanolasers on Silicon, Pave Way for on-Chip Photonics

They describe their work in a paper to be published Feb. 6 in an advanced online issue of the journalNature Photonics.

"Our results impact a broad spectrum of scientific fields, including materials science, transistor technology, laser science, optoelectronics and optical physics," said the study's principal investigator, Connie Chang-Hasnain, UC Berkeley professor of electrical engineering and computer sciences.

The increasing performance demands of electronics have sent researchers in search of better ways to harness the inherent ability of light particles to carry far more data than electrical signals can. Optical interconnects are seen as a solution to overcoming the communications bottleneck within and between computer chips.

Because silicon, the material that forms the foundation of modern electronics, is extremely deficient at generating light, engineers have turned to another class of materials known as III-V (pronounced"three-five") semiconductors to create light-based components such as light-emitting diodes (LEDs) and lasers.

But the researchers pointed out that marrying III-V with silicon to create a single optoelectronic chip has been problematic. For one, the atomic structures of the two materials are mismatched.

"Growing III-V semiconductor films on silicon is like forcing two incongruent puzzle pieces together," said study lead author Roger Chen, a UC Berkeley graduate student in electrical engineering and computer sciences."It can be done, but the material gets damaged in the process."

Moreover, the manufacturing industry is set up for the production of silicon-based materials, so for practical reasons, the goal has been to integrate the fabrication of III-V devices into the existing infrastructure, the researchers said.

"Today's massive silicon electronics infrastructure is extremely difficult to change for both economic and technological reasons, so compatibility with silicon fabrication is critical," said Chang-Hasnain."One problem is that growth of III-V semiconductors has traditionally involved high temperatures -- 700 degrees Celsius or more -- that would destroy the electronics. Meanwhile, other integration approaches have not been scalable."

The UC Berkeley researchers overcame this limitation by finding a way to grow nanopillars made of indium gallium arsenide, a III-V material, onto a silicon surface at the relatively cool temperature of 400 degrees Celsius.

"Working at nanoscale levels has enabled us to grow high quality III-V materials at low temperatures such that silicon electronics can retain their functionality," said Chen.

The researchers used metal-organic chemical vapor deposition to grow the nanopillars on the silicon."This technique is potentially mass manufacturable, since such a system is already used commercially to make thin film solar cells and light emitting diodes," said Chang-Hasnain.

Once the nanopillar was made, the researchers showed that it could generate near infrared laser light -- a wavelength of about 950 nanometers -- at room temperature. The hexagonal geometry dictated by the crystal structure of the nanopillars creates a new, efficient, light-trapping optical cavity. Light circulates up and down the structure in a helical fashion and amplifies via this optical feedback mechanism.

The unique approach of growing nanolasers directly onto silicon could lead to highly efficient silicon photonics, the researchers said. They noted that the miniscule dimensions of the nanopillars -- smaller than one wavelength on each side, in some cases -- make it possible to pack them into small spaces with the added benefit of consuming very little energy

"Ultimately, this technique may provide a powerful and new avenue for engineering on-chip nanophotonic devices such as lasers, photodetectors, modulators and solar cells," said Chen.

"This is the first bottom-up integration of III-V nanolasers onto silicon chips using a growth process compatible with the CMOS (complementary metal oxide semiconductor) technology now used to make integrated circuits," said Chang-Hasnain."This research has the potential to catalyze an optoelectronics revolution in computing, communications, displays and optical signal processing. In the future, we expect to improve the characteristics of these lasers and ultimately control them electronically for a powerful marriage between photonic and electronic devices."

The Defense Advanced Research Projects Agency and a Department of Defense National Security Science and Engineering Faculty Fellowship helped support this research.

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Roaches Inspire Robotics: Researchers Use Common Cockroach to Fine-Tune Robots of the Future

Prof. Amir Ayali of Tel Aviv University's Department of Zoology says the study of cockroaches has already inspired advanced robotics. Robots have long been based on these six-legged houseguests, whose nervous system is relatively straightforward and easy to study. But until now, walking machines based on the cockroach's movement have been influenced by outside observations and mainly imitate the insect's appearance, not its internal mechanics.

He and his fellow researchers are delving deeper into the neurological functioning of the cockroach. This, he says, will give engineers the information they need to design robots with a more compact build and greater efficiency in terms of energy, time, robustness and rigidity. Such superior robotics can be even used to explore new terrain in outer space.

This research was recently presented at the International Neuroethology conference in Spain as well as the Israeli Neuroscience Meeting in December.

Roach control systems as the ideal model

According to Prof. Ayali, it's clear why robotics have been inspired by these unsavory insects. A cockroach is supported by at least three legs at all times during movement, which provides great stability."Not only do cockroaches arguably exhibit one of the most stable ways to walk, called a tripod gate," he explains,"but they move equally quickly on every kind of terrain. Their speed and stability is almost too good to be true."

In their lab, Prof. Ayali and his fellow researchers are conducting a number of tests to uncover the mysteries of the cockroach's nervous system, studying how sensory feedback from one leg is translated to the coordination of all the other legs. Their analysis of the contribution of each leg is shared with collaborating scientists at Princeton University, who use the information to construct models and simulations of insect locomotion.

Insects, says Prof. Ayali, utilize information from the environment around them to determine how they will move. Sensors give them data about the terrain they are encountering and how they should approach it. How this information transfers to the insect's legs is central to understanding how to mimic their locomotion.

An army of robotic insects

Cockroaches are not the only insects that have captured the scientific imagination. Projects that highlight both the flight of the locust and the crawling of the soft-bodied caterpillar are also underway.

Locusts are amazing flyers, Prof. Ayali notes. Scientists are studying both their aerodynamic build and their energy metabolism for long-distance flights. Recordings of their nervous systems and simultaneous video tracking to observe the movement of their wings during flight can be expected to lead to better technology for miniscule flying robots.

As for caterpillars, engineers are trying to recreate in soft-bodied robots what they call the creatures"endless degrees of freedom of movement.""Caterpillars are not confined by a stiff structure -- they have no rigid skeletons," says Prof. Ayali."This is exactly what makes them unique."

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Making a Point: Method Prints Nanostructures Using Hard, Sharp 'Pen' Tips Floating on Soft Polymer Springs

Hard-tip, soft-spring lithography (HSL) rolls into one method the best of scanning-probe lithography -- high resolution -- and the best of polymer pen lithography -- low cost and easy implementation.

HSL could be used in the areas of electronics (electronic circuits), medical diagnostics (gene chips and arrays of biomolecules) and pharmaceuticals (arrays for screening drug candidates), among others.

To demonstrate the method's capabilities, the researchers duplicated the pyramid on the U.S. one-dollar bill and the surrounding words approximately 19,000 times at 855 million dots per square inch. Each image consists of 6,982 dots. (They reproduced a bitmap representation of the pyramid, including the"Eye of Providence.") This exercise highlights the sub-50-nanometer resolution and the scalability of the method.

The results will be published Jan. 27 by the journalNature.

"Hard-tip, soft-spring lithography is to scanning-probe lithography what the disposable razor is to the razor industry," said Chad A. Mirkin, the paper's senior author."This is a major step forward in the realization of desktop fabrication that will allow researchers in academia and industry to create and study nanostructure prototypes on the fly."

Mirkin is the George B. Rathmann Professor of Chemistry in the Weinberg College of Arts and Sciences and professor of medicine, chemical and biological engineering, biomedical engineering and materials science and engineering and director of Northwestern's International Institute for Nanotechnology.

Micro- and nanolithographic techniques are used to create patterns and build surface architectures of materials on a small scale.

Scanning probe lithography, with its high resolution and registration accuracy, currently is a popular method for building nanostructures. The method is, however, difficult to scale up and produce multiple copies of a device or structure at low cost.

Scanning probe lithographies typically rely on the use of cantilevers as the printing device components. Cantilevers are microscopic levers with tips, typically used to deposit materials on surfaces in a printing experiment. They are fragile, expensive, cumbersome and difficult to implement in an array-based experiment.

"Scaling cantilever-based architectures at low cost is not trivial and often leads to devices that are difficult to operate and limited with respect to the scope of application," Mirkin said.

Hard-tip, soft-spring lithography uses a soft polymer backing that supports sharp silicon tips as its"print head." The spring polymer backing allows all of the tips to come in contact with the surface in a uniform manner and eliminates the need to use cantilevers. Essentially, hard tips are floating on soft polymeric springs, allowing either materials or energy to be delivered to a surface.

HSL offers a method that quickly and inexpensively produces patterns of high quality and with high resolution and density. The prototype arrays containing 4,750 tips can be fabricated for the cost of a single cantilever-based tip and made in mass, Mirkin said.

Mirkin and his team demonstrated an array of 4,750 ultra-sharp silicon tips aligned over an area of one square centimeter, with larger arrays possible. Patterns of features with sub-50-nanometer resolution can be made with feature size controlled by tip contact time with the substrate.

They produced patterns"writing" with molecules and showed that as the tips push against the substrate the flexible backing compresses, indicating the tips are in contact with the surface and writing is occurring. (The silicon tips do not deform under pressure.)

"Eventually we should be able to build arrays with millions of pens, where each pen is independently actuated," Mirkin said.

The researchers also demonstrated the ability to use hard-tip, soft-spring lithography to transfer mechanical and electrical energy to a surface.

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World's First Programmable Nanoprocessor: Nanowire Tiles Can Perform Arithmetic and Logical Functions

The groundbreaking prototype computer system, described in a paper appearing in the journalNature, represents a significant step forward in the complexity of computer circuits that can be assembled from synthesized nanometer-scale components.

It also represents an advance because these ultra-tiny nanocircuits can be programmed electronically to perform a number of basic arithmetic and logical functions.

"This work represents a quantum jump forward in the complexity and function of circuits built from the bottom up, and thus demonstrates that this bottom-up paradigm, which is distinct from the way commercial circuits are built today, can yield nanoprocessors and other integrated systems of the future," says principal investigator Charles M. Lieber, who holds a joint appointment at Harvard's Department of Chemistry and Chemical Biology and School of Engineering and Applied Sciences.

The work was enabled by advances in the design and synthesis of nanowire building blocks. These nanowire components now demonstrate the reproducibility needed to build functional electronic circuits, and also do so at a size and material complexity difficult to achieve by traditional top-down approaches.

Moreover, the tiled architecture is fully scalable, allowing the assembly of much larger and ever more functional nanoprocessors.

"For the past 10 to 15 years, researchers working with nanowires, carbon nanotubes, and other nanostructures have struggled to build all but the most basic circuits, in large part due to variations in properties of individual nanostructures," says Lieber, the Mark Hyman Professor of Chemistry."We have shown that this limitation can now be overcome and are excited about prospects of exploiting the bottom-up paradigm of biology in building future electronics."

An additional feature of the advance is that the circuits in the nanoprocessor operate using very little power, even allowing for their miniscule size, because their component nanowires contain transistor switches that are"nonvolatile."

This means that unlike transistors in conventional microcomputer circuits, once the nanowire transistors are programmed, they do not require any additional expenditure of electrical power for maintaining memory.

"Because of their very small size and very low power requirements, these new nanoprocessor circuits are building blocks that can control and enable an entirely new class of much smaller, lighter weight electronic sensors and consumer electronics," says co-author Shamik Das, the lead engineer in MITRE's Nanosystems Group.

"This new nanoprocessor represents a major milestone toward realizing the vision of a nanocomputer that was first articulated more than 50 years ago by physicist Richard Feynman," says James Ellenbogen, a chief scientist at MITRE.

Co-authors on the paper included four members of Lieber's lab at Harvard: Hao Yan (Ph.D. '10), SungWoo Nam (Ph.D. '10), Yongjie Hu (Ph.D. '10), and doctoral candidate Hwan Sung Choe, as well as collaborators at MITRE.

The research team at MITRE comprised Das, Ellenbogen, and nanotechnology laboratory director Jim Klemic. The MITRE Corporation is a not-for-profit company that provides systems engineering, research and development, and information technology support to the government. MITRE's principal locations are in Bedford, Mass., and McLean, Va.

The research was supported by a Department of Defense National Security Science and Engineering Faculty Fellowship, the National Nanotechnology Initiative, and the MITRE Innovation Program.

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Hydrogels Used to Make Precise New Sensor

The"diffraction-based" sensors are made of thin stripes of a gelatinous material called a hydrogel, which expands and contracts depending on the acidity of its environment.

Recent research findings have demonstrated that the sensor can be used to precisely determine pH -- a measure of how acidic or basic a liquid is -- revealing information about substances in liquid environments, said Cagri Savran (pronounced Chary Savran), an associate professor of mechanical engineering at Purdue University.

The sensor's simple design could make it more practical than other sensors in development, he said.

"Many sensors being developed today are brilliantly designed but are too expensive to produce, require highly skilled operators and are not robust enough to be practical," said Savran, whose work is based at Purdue's Birck Nanotechnology Center in the university's Discovery Park.

New findings show the technology is highly sensitive and might be used in chemical and biological applications including environmental monitoring in waterways and glucose monitoring in blood.

"As with any novel platform, more development is needed, but the detection principle behind this technology is so simple that it wouldn't be difficult to commercialize," said Savran, who is collaborating with another team of researchers led by Babak Ziaie, a Purdue professor of electrical and computer engineering and biomedical engineering.

Findings are detailed in a paper presented during the IEEE Sensors 2010 Conference in November and also published in the conference proceedings. The paper was written by postdoctoral researcher Chun-Li Chang, doctoral student Zhenwen Ding, Ziaie and Savran.

The flexible, water-insoluble hydrogel is formed into a series of raised stripes called a"diffraction grating," which is coated with gold on both the stripe surfaces and the spaces in between. The stripes expand and contract depending on the pH level of the environment.

Researchers in Ziaie's lab fabricated the hydrogel, while Savran's group led work in the design, development and testing of the diffraction-based sensor.

The sensors work by analyzing laser light reflecting off the gold coatings. Reflections from the stripes and spaces in between interfere with each other, creating a"diffraction pattern" that differs depending on the height of the stripes.

These diffraction patterns indicate minute changes in the movement of the hydrogel stripes in response to the environment, in effect measuring changes in pH.

"By precise measurement of pH, the diffraction patterns can reveal a lot of information about the sample environment," said Savran, who by courtesy is an associate professor of biomedical engineering and electrical and computer engineering."This technology detects very small changes in the swelling of the diffraction grating, which makes them very sensitive."

The pH of a liquid is recorded on a scale from 0 to 14, with 0 being the most acidic and 14 the most basic. Findings showed the device's high sensitivity enables it to resolve changes smaller than one-1,000th on the pH scale, measuring swelling of only a few nanometers. A nanometer is about 50,000 times smaller than the finest sand grain.

"We know we can make them even more sensitive," Savran said."By using different hydrogels, gratings responsive to stimuli other than pH can also be fabricated."

The work is ongoing.

"It's a good example of collaborations that can blossom when labs focusing on different research are located next to each other," Savran said."Professor Ziaie's lab was already working with hydrogels, and my group was working on diffraction-based sensors. Hearing about the hydrogels work next door, one of my postdoctoral researchers, Chun-Li Chang thought of making a reflective diffraction grating out of hydrogels."

The Office of Technology Commercialization of the Purdue Research Foundation has filed for U.S. patent protection on the concept.

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